How to unstake and withdraw DOT (KSM/EDG)

First, open [DApp] – [Staking Tools]

Make sure you are in ‘Stash account’ mode, and click ‘Unbond’

Enter the unbonding amount

After the unbonding period completed (for DOT is 28 days)

Switch to Controller account mode

Then you will see the ‘Withdraw’ button besides dismissed DOT, click the button and sign the transaction, then you will get these DOT to your balance.

If you have participate Polkadot council election, you will need to quit Polkadot election lock as well, details:

How to quit Polkadot election lock